• Investigation Of Effects Of Two Flame Retardants On The Fire Characterisit Ics Of Flexible Poly Ether Foam

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    • 4.5    Flame duration
      The results shown in Table 10, Fig. 7 clearly indicate that these flame retardant suppressed flame duration a lot as much as seven – fold at their highest conc entration. When a part of combustible material is gradually heated, its temperature is increased; the molecules / atoms making it vibrate more. As temperature continues to rise molecular motions increases further to a point when bonds are ruptured and pyrolysates some of which interact with oxygen in the environment in exothermic reaction [80,81]. At this stage, flame, a region of visible gaseous reaction is produced. Thus, the duration or the extent of flame is directly linked to the sustenance of the stream of pyrolysis products. It is therefore expect that any technique that depresses the egress of the pyrolysates would decrease flame duration [82].
      This is the reason why the presence of these two flame retardants decrease flame duration. Comparatively , it is clear that the melamine is a better flame duration suppressant.

      4.6    CONCLUSION
      The following conclusion can be made from the results of the study.
      The two flame retardants, melamine and tri ammonium orthophosphate, were successfully incorporated in the production of flexible polyurethane foams under the production conditions of a commercial foam industry. Hence, it is clear that the two flame retardants are suitable for producing commercial foams that are affordable and maintains the quality.
      The two flame retardants are effective in reducing the after - glow time (AGT), flame duration time and propagation rate properties. The reduction of these fire char5acterisitcis is paramount to reduction of flammability of the p olyurethane foam which leads to safety of lives and properties.
      Dramatic increase in ignition time and charring percentage shown by tri ammonium orthophosphate is evidence that its incorporation    into    polyurethane    will    delay    burning    on occasions of fire, thereby increases time for safety of life and properties.
      However, melamine showed better impact for after -glow time and flame duration time, while tri ammonium orthophosphate is preferred for reduction of ignition time and propagation rate due to increase in high percentage charring.
      4.7    RECOMMENDATION
      1.    The two flame retardants are recommended for use for retarding commercial polyurethane foams, that will reduce the incident of fire and destruction of life and properties.
      2.    Tri ammonium ortho phosphate is preferred for retarding flexible polyurethane foams to melamine.
      3.    The commercial foam industrie s that are not incorporating any flame retardants to their products, because of cost, can now start to make use of these two flame retardants because of its availabil ity and low cost.

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    • ABSRACT - [ Total Page(s): 1 ]ABSTRACTThis work studied the effects of two flame retardants on the fire characteristics of flexible polyether foam samples. Various concentrations of two flame retardants melamine and tri ammonium orthophosphate have been successfully incorporated into flexible polyurethane foam. Results of the analyses carried out on the various foam samples showed that by appropriate incorporation of the two flame retardants, the flammability properties (After glow time (AGT), ignition time, flame duration t ... Continue reading---

         

      APPENDIX A - [ Total Page(s): 2 ] ... Continue reading---

         

      LIST OF TABLES - [ Total Page(s): 1 ]LIST OF TABLE STable 1:    Classification of flame retardants based on nature of compoundsTable 2:    Basic formulatio n of flexible polyurethane foam Table 3:    Application of polyurethane foamsTable 4:    Formulation for polyurethane retarded with melamineTable 5:    Formulation for polyurethane retarded with tri ammonium orthophosphateTable 6:    After glow time result Table 7:    Ignition time result Table 8:    Flame propagation resultTable 9:    The percentage c ... Continue reading---

         

      LIST OF FIGURES - [ Total Page(s): 1 ]LIST OF FIGURESFig. 1:    The combustion process of plasticsFig. 2:    Classes of flame reta rdants based on durabilityFig. 3:        Effects of concentration of flame retardants on After glow time of flexible polyurethane foam.Fig. 4:        Effects of concentration of flame retardants on ignition time of flexible polyurethane foam.Fig. 5:        Effects of concentration of flame retardants on flame propagation of flexible polyurethane foam.Fig. 6:        Effects o ... Continue reading---

         

      TABLE OF CONTENTS - [ Total Page(s): 1 ]TABLE OF CONTENTSTitle page    Certification  Dedication  Acknowledgements  Abstract Table of contents  List of table    List of figures   CHAPTER ONE INTRODUCTION    1.1    Background of the study   1.2    Significance of the Research.    1.3    Scope of the Study  1.4    The objectives of the Study;  CHAPTER TWO2.1    Fire, Pyrol yses and Combustion    2.1.2 Pyrolysis of Plastics    2.1.3    Pyrolysis of Polyurethane foams    2.2    Flame Ret ... Continue reading---

         

      CHAPTER ONE - [ Total Page(s): 2 ]The rising time occurs when foam mix starts to rise until it gets to a full block height. At this stage the isocyanate reacts with water to generate carbon dioxide which causes the rise. The formation of the carbon dioxide through the intermediate carbamic acids gives.RH = C = O + H – O – H    RNH COOH        RNH 2 + CO2The curing time is the reaction process that leads to completion of the polymerization reaction that is usually greater than 15 hours. Polyurethane can ei ... Continue reading---

         

      CHAPTER TWO - [ Total Page(s): 13 ]The requirements for good catalytic activity are: (a) nucleophilic enough to attack the carbon of the isocy anate group, (b) ability to form an active hydrogen amine complex, and (c) solubility in water with the ability to form hydrogen bonds with water.Since electron accessibility is also usually measured by the basicity, the catalytic activity is found to generally increase as the basicity increase. Thus, a plot of pH vs. catalytic activity usually yields linear behavior. Howe ver, exception e ... Continue reading---

         

      CHAPTER THREE - [ Total Page(s): 2 ]CHAPTER THREEEXPERIMENTAL3.1    Materials and MethodsThe materials include:1.    Polyol2.    Toluene diisocynate (TDI)3.    Silicone4.    Dimethylethanol amine5.    Water6.    Stanous octate or Tin II7.    Melamine8.    Tri ammonium orthophosphateMaterial (1 – 6) above were all obtained from Marthar foams industries Ltd., Nkpor – Obosi Road, Onitsha Anambra State Nigeria.Melamine and tri ammonium orthophosphate were bought from Laboratory of National Rese ... Continue reading---

         

      REFRENCES - [ Total Page(s): 2 ]REFERENCES1.    National Fire Protection Association (2008) fire loss in US during 2005, abridg ed report (http://www.usfa. gov/statistic/National) ( Retrieved, February 28, 2010)2.    J .M. Avento, (1980), Flame Retardant , an Overview. Encyclop aedia of Chemical Technology Vol. 10, J ohn Wiley & Sons. New York , pp 348 – 372.3.    A.N. Eboatu (1992) Fire, Flammability and Fire Fighting. Anchor Ednal Press, Lagos, p.254.    X. Nguyen Huy (2008) “Flame Reta rdants” ... Continue reading---